420 Stainless Steel: Composition, Properties & Hardness

420 Stainless Steel: Composition, Properties
420 Stainless Steel: Composition, Properties

420 stainless steel is a hardenable martensitic stainless steel that contains a minimum of 12% chromium, which provides good corrosion resistance properties, Its best corrosion resistance is achieved when the metal is hardened and surface ground or polished. 420 grade has a higher carbon content than is designed to enhance strength and hardness characteristics, however, the corrosion resistance of 420 stainless steel is not as good as the common austenitic grades.

420 stainless steel has good ductility in the annealed condition but can be hardened to a minimum Rockwell hardness of 50 HRC, which is the highest hardness of the 12% chromium grades, the typical application is for knives. 420 stainless steel is magnetic due to its microstructure of martensitic.

The hardness of 420 stainless steel: Rockwell HRB 96 max.

420 stainless steel heat treatment: Heat to 1500-1650°F (816-899°C), cool slowly

420 stainless steel melting point: 2649 – 2750°F (1454 – 1510°C)

420 Stainless Steel Chemical Composition

The chemical composition of 420 stainless steel contains 12–14% chromium (Cr) and iron, high carbon content (min 0.15%), and less nickel content (0.75% Max).

ASTM
AISI (UNS)
C,Si, MaxMn, MaxP, MaxS, MaxCrNi, MaxMo, MaxIron
ASTM A240 420SS 420 (UNS S42000)0.15, min1.001.000.0400.03012.0-14.00.750.50Bal.
ASTM A276 420SS 420 (UNS S42000)0.15, min1.001.000.0400.03012.0-14.0Bal.
EN10088-2 1.4028 0.26-0.351.001.500.0400.01512.0-14.0Bal.
EN10088-2 1.4021 0.16-0.251.001.500.0400.01512.0-14.0 Bal

420 Stainless Steel Mechanical Properties

empering Temperature (°C)Tensile Strength (MPa)Yield Strength
0.2% Proof (MPa)
Elongation
(% in 50mm)
Hardness Brinell
(HB)
Annealed *65534525241 max
399°F (204°C)1600136012444
600°F (316°C)1580136514444
800°F (427°C)1620142010461
1000°F (538°C)1305109515375
1099°F (593°C)103581018302
1202°F (650°C)89568020262
* Annealed tensile properties are typical for Condition A of ASTM A276; annealed hardness is the specified maximum.

420 Stainless Steel Physical Properties

The table below provides the physical properties of grade 420 in their annealed state:

GradeDensity (Kg/M3)Elastic Modulus (GPa)Mean Coefficient Of Thermal Expansion
(Μm/M/°C)
Thermal Conductivity
(W/M.K)
Specific Heat 0-100°C
(J/Kg.K)
Electrical Resistivity (NΩ.M)
0-100°C0-315°C0-538°CAt 100°CAt 500°C
420780020010.310.811.724.9460550

420 Stainless Steel Equivalent

EU
EN
USA
Germany
DIN,WNr
Japan
JIS
France
AFNOR
England
BS
China
GB
Sweden
SS
Poland
PN
Czechia
CSN
Russia
GOST
EU
EN
USA
Germany
DIN,WNr
Japan
JIS
France
AFNOR
England
BS
China
GB
Sweden
SS
Poland
PN
Czechia
CSN
Russia
GOST
X20Cr13 (1.4021)420/S42010X20Cr13SUS420J1X20Cr13Z20C13420S29420S372Cr13X20Cr1323032H131702220KH13

Features

Grade 420 stainless steel is a high-carbon steel with a minimum chromium content of 12%. Like other martensitic stainless steels, grade 420 can also be hardened through heat treatment. Martensitic stainless steels are ones with high hardness and high carbon content. These steels are generally fabricated using methods that require hardening and tempering treatments. The operating conditions of martensitic steels are affected by loss of material strength at high temperatures and a decrease in ductility at negative temperatures. AISI 420 steel provides both outstanding corrosion resistance and exceptional wear resistance.

  • High hardness: stainless steel 420 has a high degree of hardness, which can be obtained through heat treatment. This makes it widely used in the manufacture of knives, surgical instruments and industrial parts.
  • Good corrosion resistance: 420 SS has good corrosion resistance and can resist many chemicals, including some acids and salt solutions. However, compared with other stainless steels, the corrosion resistance of 420 stainless steel is relatively low.
  • Easy machining: 420 grade has good plasticity and machinability before heat treatment, easy to forge, cold drawing, milling and cutting and other machining operations.
  • Excellent grinding properties: 420 has good grinding properties, so it can be used in applications such as the manufacture of knives and blades that need to achieve a sharp cutting edge.
  • Moderate strength and wear resistance: Type 420 has moderate tensile strength and wear resistance, making it widely used in the manufacture of parts that require wear resistance.
  • It is important to note that due to its high carbon content and low chromium content, 420 grade may experience corrosion problems in some extreme environments such as high temperatures and highly corrosive environments. Therefore, use needs to be evaluated and selected based on the specific application.

Corrosion Resistance

Under hardened conditions, grade 420 steels are resistant to fresh water, alkalis, air, foods and mild acids. The steel grades with a smooth surface finish have excellent performance. The corrosion resistance properties of grade 420 will tend to fall under annealed conditions. The corrosion resistance of grade 420 is lower than that of grade 430 Ferritic alloys with 17% chromium, grade 410 steel and other austenitic grades. Grade 420 steels have good corrosion resistance against food, but continuous exposure of metals to unwashed food substances can lead to pitting corrosion.

Heat Resistance

Its heat resistance depends on the content of its alloying elements and heat treatment process.

Typically, SS 420 has limited heat resistance and is better suited for low-temperature operating environments. Its maximum service temperature is usually 650℃. Beyond this temperature range, the stainless steel will begin to occur nitride precipitation, resulting in excessive grain growth and grain boundary corrosion, which can lead to a serious increase in the thermal embrittlement of the material.

If the heat resistance of 420 grade needs to be improved, heat treatment processes, such as solution treatment and quenching and annealing, can be performed. These treatments can improve the grain boundary structure and grain size of the material, thus improving its heat resistance.

Overall, the heat resistance of 420 SSl is low compared to other heat-resistant stainless steel and is suitable for use in low-temperature environments. For high-temperature applications, it is recommended to choose a stainless steel material with better heat resistance.

Heat Treatment

420 stainless steel is a high carbon content stainless steel with excellent corrosion resistance and mechanical properties. It can be further improved by heat treatment. Using the annealing process, grade 420 stainless steel is heated to 840 to 900°C, then slowly furnace cooled at 600°C and finally air cooled. For process annealing, Grade 420 steel is heated to 735 to 785°C and then air-cooled. For hardening, 420 grade steel is heated to 980 to 1035°C and then air or oil quenched. Temper at 150 to 370°C to obtain high hardness and good mechanical properties, but avoid tempering treatments between 425 and 600°C.

Welding

Grade 420 stainless steels are welded using welding rods, coated with grade 420 metals, to achieve high-strength joints. During the process, steels are pre-heated at 150 to 320°C and post-heated at 610 to 760°C. In the “as welded” condition, parts are welded using grade 309 filler rods to achieve ductile joints. However, grade 309 electrodes or rods are recommended for welding grade 420 steels by AS 1554.6.

Machining

Grade 420 steels can be easily machined in their annealed state, but they are difficult to machine having a hardness greater than 30HRC. One of the most readily available machined alternatives is the free-machining grade 416 steels.

The following are common processing methods for 420 stainless steel:

  • Cutting: use a shear, cutter or EDM cutter to cut 420 stainless steel. Ensure that the cutter has the proper cutting capacity and that the tool is sharp.
  • Welding: Use suitable welding methods for stainless steel, such as TIG welding or MIG welding. Pay attention to temperature control during the welding process to avoid annealing or oxidizing the steel.
  • Bending: Use mechanical bending machine or hand bending tools to bend 420 stainless steel plate or bar into the desired shape. Pay attention to choose the appropriate bending radius to avoid cracks caused in the bending process.
  • Milling: use milling machine or gantry machining center to mill 420 stainless steel. Select appropriate tools and cutting parameters to ensure a smooth cutting process and a smooth surface.
  • Grinding: Use a sander, polisher or hand sandpaper to grind the surface of 420 stainless steel to the desired finish. Select different grain sizes of grinding wheels or sandpaper as required.
  • Drilling: Drilling operations are performed using a drill press or hand-held drill. Use cobalt or titanium drill bits to ensure stable cutting and cooling lubrication.
  • Turning: Use a lathe to turn 420 stainless steel. Select the proper turning tool, cutting speed and feed to obtain the desired accuracy and surface quality.

Applications

420 stainless steel has high hardness and wear resistance, as well as good corrosion resistance, and can be used to manufacture knives, blades, surgical instruments, bearing components, assembly parts, and so on. The material is also easy to process and malleable, easy to be processed into various shapes and sizes through cutting, forging, heat treatment and other processes. It is not usually used at temperatures exceeding 800oF (427oC) due to quick hardening and loss of corrosion resistance.

  • Knife manufacturing: 420 stainless steel has good cutting performance and hardness, commonly used in the manufacture of blades, handles, knives scalpels and other medical devices.
  • Pressure vessels: Because of its excellent corrosion resistance and high strength, 420 stainless steel is widely used in the manufacture of pressure vessels, tanks and pipelines in the fields of chemical industry, petroleum, natural gas, and so on.
  • Food processing equipment: 420 stainless steel meets hygiene standards, has excellent corrosion resistance, and is easy to cut and process, often used in the manufacture of food processing equipment, knives, and cutting instruments.
  • Aerospace: 420 stainless steel’s strength and corrosion resistance make it an important material in the aerospace industry, used to manufacture aircraft parts, propellers, shafts, etc.
  • Chemical equipment: Because 420 stainless steel can resist the erosion of strong acids, alkalis, salts and other corrosive media, it is widely used in the chemical industry to manufacture chemical equipment, storage tanks, pipelines and so on.
  • Medical equipment: 420 stainless steel has good corrosion resistance, high-temperature strength, and low-temperature toughness, and is widely used in the manufacture of medical equipment, surgical instruments, dental instruments and so on.

Forms

420 Stainless Steel Specifications

  • A 240/A 240M Chromium and Chromium-Nickel Stainless Steel Plate, Sheet, and Sliip for Pressure Vessels and for General Applications
  • A 276 Stainless Steel Bars and Shapes
  • EN 10088-2, Stainless steels. Technical delivery conditions for sheet/plate and strip of corrosion-resisting steels for general purposes


What Is the Difference Between 420 and 304 Stainless Steel?

420 is a martensitic stainless steel grade. As such, its major alloying elements are chromium and carbon, with small amounts of manganese, silicon, and sometimes molybdenum and nickel. 304 is an austenitic stainless steel alloy that contains a substantial amount of nickel along with more chromium than 420. but the carbon level is much lower than that of 420.

One significant difference lies in their corrosion resistance. 304 stainless steel is good resistant to corrosion, while 420 grade offers good corrosion resistance in mild environments, it is not as resistant as 304 stainless steel. In terms of strength and hardness, 420 steel excels. 304 stainless steel provides better ductility and toughness, but it is not as hard or strong as 420 alloy.